REACTIONS INVOLVING FLUORIDE-ION .39. REACTIONS OF PERFLUORINATED DIENES WITH OXYGEN AND SULFUR NUCLEOPHILES

被引：23

作者：

BRISCOE, MW ^{[1
]}

CHAMBERS, RD ^{[1
]}

MULLINS, SJ ^{[1
]}

NAKAMURA, T ^{[1
]}

VAUGHAN, JFS ^{[1
]}

机构：

[1] UNIV DURHAM,DEPT CHEM,SCI LABS,DURHAM DH1 3LE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 21期

关键词：

D O I：

10.1039/p19940003119

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The order of reactivity of perfluorinated dienes towards methanol is 3 > 2 much greater than 1 and the process is activated by release of angle strain. The diene 1 is hydrolysed to give perfluorotetramethyl-furan and the corresponding thiophene, is obtained by an analogous process using K2S. Hydrolysis of compounds 2 and 3 yields diketones that are strong acids. Reactions of phenols and thiophenols with 1 give aryl ethers and sulfides and difunctional nucleophiles react with 1 to give potential polymer precursors.

引用

页码：3119 / 3124

页数：6

共 13 条

[1]

BASSETTI M, 1988, TETRAHEDRON, V44, P2997

[2]

BORIACK CJ, 1978, TETRAHEDRON LETT, P1015

[3] THE PREPARATION AND SOME PROPERTIES OF THE C4F8 OLEFINS [J].

BRICE, TJ ;

LAZERTE, JD ;

HALS, LJ ;

PEARLSON, WH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (11) :2698-2702

[4] REACTIONS INVOLVING FLUORIDE-ION .38. NEW FLUORINATED DIENES BY DEFLUORINATION [J].

BRISCOE, MW ;

CHAMBERS, RD ;

MULLINS, SJ ;

NAKAMURA, T ;

VAUGHAN, JFS ;

DRAKESMITH, FG .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1994, (21) :3115-3118

[5] REACTIONS INVOLVING FLUORIDE-ION .29. REACTIONS OF PERFLUORO-2,3-DIMETHYLBUTA-1,3-DIENE [J].

BRYCE, MR ;

CHAMBERS, RD ;

LINDLEY, AA ;

FIELDING, HC .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1983, (10) :2451-2454

[6] REACTIONS INVOLVING FLUORIDE-ION .16. NUCLEOPHILIC-ATTACK ON A PERFLUOROTETRA-ALKYLETHYLENE AND A SYNTHESIS OF PERFLUOROTETRAMETHYLFURAN [J].

CHAMBERS, RD ;

LINDLEY, AA ;

PHILPOT, PD ;

FIELDING, HC ;

HUTCHINSON, J ;

WHITTAKER, G .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1979, (01) :214-219

[7]

CHAMBERS RD, 1965, ADV FLUORINE CHEM, V4, P50

[8] NITROSATION OF ACETYLACETONE (PENTANE-2,4-DIONE) AND SOME OF ITS FLUORINATED DERIVATIVES [J].

CROOKES, MJ ;

ROY, P ;

WILLIAMS, DLH .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1989, (08) :1015-1019

[9]

KNUNYANTS IL, 1956, IAN SSSR KH, P1353

[10]

KOBAYASHI Y, 1978, TETRAHEDRON LETT, P1019

← 1 2 →