MIXED ORGANOFLUORINE-ORGANOSILICON CHEMISTRY .5. REACTIVITY OF 1-ARYL (OR ALKYL)-1-TRIALKYLSILYL PERFLUOROALKANOLS

被引：22

作者：

DONDY, B ^{[1
]}

DOUSSOT, P ^{[1
]}

PORTELLA, C ^{[1
]}

机构：

[1] UFR SCI,CNRS,REARRANGEMENTS THERM & PHOTOCHIM LAB,F-51062 REIMS,FRANCE

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 03期

关键词：

1-TRIALKYLSILYL PERFLUOROALKANOLS; POLYFLUOROENAMINONES; POLYFLUOROPYRAZOLES; 1-PERFLUOROALKYL-1-TRIALKYLSILYLOXYALKANE;

D O I：

10.1016/0040-4039(94)85066-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title alcohols react,with amines and hydrazines to yield perfluoro-beta-enaminones and pyrazoles respectively. With ammonia, they lead either to the beta-enaminone or to the silylether of the corresponding secondary alcohol, depending on the ammonia concentration.

引用

页码：409 / 412

页数：4