SYNTHESIS OF DINUCLEAR ANIONIC COMPLEXES [CP-STARRH(CO)]2- AND [CP-STARRH(CO)]22- BY DISSOLVING METAL REDUCTION AND R[CP-STARRH(CO)]2- BY ADDITION OF ALKYLLITHIUM REAGENTS ACROSS THE METAL-METAL DOUBLE-BOND OF [CP-STARRH(CO)]2 - STEREOSELECTIVE SYNTHESIS OF SYMMETRICAL AND MIXED DINUCLEAR DIALKYLS [CP-STAR2RH2(CO)2(R1)(R2)] AND A STUDY OF THEIR LIGAND-INDUCED FRAGMENTATION REACTIONSS

被引：17

作者：

KRAUSE, MJ ^{[1
]}

BERGMAN, RG ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY, DEPT CHEM, BERKELEY, CA 94720 USA

来源：

ORGANOMETALLICS | 1986年 / 5卷 / 10期

关键词：

D O I：

10.1021/om00141a029

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：2097 / 2108

页数：12

共 109 条

[1] CHEMISTRY OF THE METAL-CARBONYLS .81. HOMONUCLEAR AND HETERONUCLEAR DI-METAL AND TRI-METAL CARBONYL-COMPLEXES DERIVED FROM DICARBONYL-(PENTAMETHYLCYCLOPENTADIENYL)RHODIUM - X-RAY CRYSTAL-STRUCTURE OF [MN-RH(MU-CO)2(CO)2(ETA-C5H5)(ETA-C5ME5)] [J].

ALDRIDGE, ML ;

GREEN, M ;

HOWARD, JAK ;

PAIN, GN ;

PORTER, SJ ;

STONE, FGA ;

WOODWARD, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (07) :1333-1340

[2] CARBON-MONOXIDE DISSOCIATION REACTION OF (H5-C5H5)2MO2(CO)6 WITH DIPHENYLACETYLENE [J].

AMER, S ;

POE, A .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 209 (02) :C31-C33

[3] CARBON CARBON BOND FORMATION IN THE REDUCTIVE COUPLING OF KETONES BY THE DOUBLY BONDED DITUNGSTEN(IV) ALKOXIDES W2CL4(MU-OR)2(OR)2(ROH)2 [J].

ANDERSON, LB ;

COTTON, FA ;

DEMARCO, D ;

FALVELLO, LR ;

TETRICK, SM ;

WALTON, RA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (17) :4743-4749

[4]

[Anonymous], 1976, PROG INORG CHEM

[5] A HYDRIDO(MU-HYDRIDO)METHYLDIPLATINUM(II) COMPLEX - REDUCTIVE ELIMINATION OF METHANE INDUCED BY REACTION WITH AN ALKYNE [J].

AZAM, KA ;

PUDDEPHATT, RJ .

ORGANOMETALLICS, 1983, 2 (10) :1396-1399

[6] THE ANALOGY BETWEEN ALKENES AND THE DINUCLEAR SPECIES [CORH(MU-CO)2(ETA-C5ME5)2] [RHRH(MU-CO)2(ETA-C5ME5)2] - DYNAMIC NUCLEAR MAGNETIC-RESONANCE, X-RAY CRYSTALLOGRAPHIC, AND EXTENDED-HUCKEL MOLECULAR-ORBITAL STUDIES OF THE BONDING BETWEEN UNSATURATED CORH AND RH2 FRAGMENTS AND THE PENTACARBONYLMOLYBDENUM GROUPAN [J].

BARR, RD ;

GREEN, M ;

HOWARD, JAK ;

MARDER, TB ;

ORPEN, AG ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1984, (12) :2757-2763

[7] ALKENE-LIKE ROTATION OF UNSATURATED RH2 AND CORH FRAGMENTS WHEN BONDED TO MOLYBDENUM PENTACARBONYL - X-RAY CRYSTAL-STRUCTURE OF [MORH2(MU-CO)2(CO)5(ETA-C5ME5)2] [J].

BARR, RD ;

GREEN, M ;

HOWARD, JAK ;

MARDER, TB ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (14) :759-760

[8] CHEMISTRY OF THE METAL-CARBONYLS .82. SYNTHESIS OF COMPLEXES WITH BONDS BETWEEN RHODIUM AND THE SUBGROUP 6 METALS - X-RAY CRYSTAL-STRUCTURE OF [CRRH(MU-CO)2(CO)2(ETA-C5ME5)(ETA-C6H6)] [J].

BARR, RD ;

GREEN, M ;

MARSDEN, K ;

STONE, FGA ;

WOODWARD, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (03) :507-512

[9] THE CYCLOADDITION OF CARBONYL-FLANKED METHYLENE BRIDGES - A NOVEL METHOD FOR THE SYNTHESIS OF METALLACYCLES [J].

BAUER, C ;

GUGGOLZ, E ;

HERRMANN, WA ;

KRIECHBAUM, G ;

ZIEGLER, ML .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1982, 21 (03) :212-213

[10] TRANSITION METAL-METHYLENE COMPLEXES .20. CONSECUTIVE CARBENE ADDITION TO A METAL-METAL DOUBLE-BOND [J].

BAUER, C ;

HERRMANN, WA .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1981, 209 (01) :C13-C16

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