SPECTROSCOPIC AND STRUCTURAL INVESTIGATION OF NICKEL(II) AND NICKEL(III) COMPOUNDS STABILIZED BY IDENTICAL P,O LIGANDS

被引：29

作者：

DUNBAR, KR

SUN, JS

QUILLEVERE, A

机构：

来源：

INORGANIC CHEMISTRY | 1994年 / 33卷 / 16期

关键词：

D O I：

10.1021/ic00094a025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A pair of Ni(II)/Ni(III) ComPlexes with an identical ligand set derived from tris(2,4,6-trimethoxyphenyl)phosphine (TMPP) has been synthesized and structurally characterized. The compound Ni(II)(TMPP-0)2 (1) exhibits a trans square-planar geometry consisting of two phosphorus and two phenoxide oxygen atoms. COMpound [Ni(III)(TMPP-0)2] [BF4] (2) obtained from the chemical oxidation of 1 possesses a distorted octahedral geometry with two mutually cis phosphorus and two phenoxide oxygen atoms in the equatorial plane and two ether methoxy oxygen atoms in axial positions.

引用

页码：3598 / 3601

页数：4

共 35 条

[1]

BEURSKENS RT, 1984, DIRDIF DIRECT METHOD

[2] NICKEL THIOETHER CHEMISTRY - A REEXAMINATION OF THE ELECTROCHEMISTRY OF [NI([9]ANES3)2]2+ - THE SINGLE-CRYSTAL X-RAY STRUCTURE OF A NICKEL(III) THIOETHER COMPLEX, [NIIII([9]ANES3)2][H5O2]3[CLO4]6 ([9]ANES3 = 1,4,7-TRITHIACYCLONONANE) [J].