REGIOSELECTIVITY IN THE FORMATION OF CYCLIC SULFONES FROM 4-ALKENESULPHONYL AND 5-ALKENESULPHONYL CHLORIDES

被引：9

作者：

CULSHAW, PN ^{[1
]}

WALTON, JC ^{[1
]}

机构：

[1] UNIV ST ANDREWS,DEPT CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 44期

关键词：

D O I：

10.1016/S0040-4039(00)97084-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alk-4-enesulphonyl chlorides and alk-5-enesulphonyl chlorides cyclise under free radical conditions mainly in the endo mode to give tetrahydrothiopyran-1,1-dioxide and thiepane- 1,1-dioxide respectively. © 1990.

引用

页码：6433 / 6436

页数：4

共 15 条

[1]

[Anonymous], [No title captured]

[2] HOMOLYTIC DISPLACEMENT AT SATURATED CARBON .9. THE REACTIONS OF TRICHLOROMETHANESULFONYL CHLORIDE WITH PENT-4-ENYLCOBALOXIMES AND WITH OLEFINS - A NOVEL ROUTE TO (TRICHLOROETHYL)SULFOLANES VIA AN SHI MECHANISM [J].

ASHCROFT, MR ;

BOUGEARD, P ;

BURY, A ;

COOKSEY, CJ ;

JOHNSON, MD ;

HUNGERFORD, JM ;

LAMPMAN, GM .

JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (10) :1751-1761

[3] CHLORINE-ACTIVATION BY REDOX-TRANSFER .4. ADDITION OF SULPHONYL CHLORIDES TO VINYLIC MONOMERS + OTHER OLEFINS [J].

ASSCHER, M ;

VOFSI, D .

JOURNAL OF THE CHEMICAL SOCIETY, 1964, (DEC) :4962-&

[4]

Beckwith A. L. J., 1980, REARRANGEMENTS GROUN, VI, P161

[5] RATE CONSTANTS AND ARRHENIUS PARAMETERS FOR THE REACTIONS OF PRIMARY, SECONDARY, AND TERTIARY ALKYL RADICALS WITH TRI-NORMAL-BUTYLTIN HYDRIDE [J].

CHATGILIALOGLU, C ;

INGOLD, KU ;

SCAIANO, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (26) :7739-7742

[6]

Chatgilialoglu C., 1988, CHEM SULPHONES SULPH, P1089

[7]

HORROWITZ A, 1975, J AM CHEM SOC, V97, P10

[8] A NON-CHAIN FREE-RADICAL MECHANISM FOR THE INSERTION OF SULFUR-DIOXIDE INTO CARBON METAL BONDS [J].

JOHNSON, MD ;

DERENNE, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 286 (03) :C47-C50

[9]

KAAFARANI M, 1987, B SOC CHIM FR, P885

[10] REACTION OF TRIFLUOROMETHANESULFONYL CHLORIDE WITH ALKENES CATALYZED BY A RUTHENIUM(II) COMPLEX [J].

KAMIGATA, N ;

FUKUSHIMA, T ;

YOSHIDA, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (20) :1559-1560

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