DURABILITY OF RADIATION-STERILIZED POLYMERS .13. THE EFFECTS OF NUCLEATING-AGENT ON THE OXIDATIVE-DEGRADATION OF POLY(PROPYLENE-CO-ETHYLENE)

The radiation stability of the random and block poly(propylene‐co‐ethylene) (CP, copolymer with 6% ethylene units) with and without nucleating agent (NA) was compared in relation to radiation sterilization of medical supplies. In both cases, it was found that the radiation stability of CP in the presence of NA was lower than that of CP without NA. Addition of NA to CP did not improve the transparency but the crystallization occurred at higher temperature. Thus, adding NA to CP has the advantage of shorter moulding time in the production of medical supplies. The radiation instability of the CP with NA was due to a different crystal structure, because the spherulite shape differs from that of CP without NA. Furthermore, by the chemiluminescence analysis, a higher oxidative degradation was observed in the sample with NA. © 1990 Hüthig & Wepf Verlag, Basel