THE AZA-DI-PI-METHANE REARRANGEMENT OF STABLE DERIVATIVES OF 2,2-DIMETHYL-4,4-DIPHENYLBUT-3-ENAL

被引：10

作者：

ARMESTO, D ^{[1
]}

HORSPOOL, WM ^{[1
]}

MANCHENO, MJ ^{[1
]}

ORTIZ, MJ ^{[1
]}

机构：

[1] UNIV DUNDEE,DEPT CHEM,DUNDEE DD1 4HN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1990年 / 08期

关键词：

D O I：

10.1039/p19900002348

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The sensitised irradiations of the semicarbazone (7a), the benzoylhydrazone (7b), and the oxime benzoate (7c) of 2,2-dimethyl-4,4-diphenylbut-3-enal afford the corresponding derivatives of 2,2-dimethylcyclopropanecarbaldehyde (8a-c) in good yield by an aza-di-π-methane rearrangement.

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页码：2348 / 2349

页数：2

相关论文

共 10 条

[1] SUBSTITUTION EFFECTS ON THE AZA-DI-PI-METHANE REARRANGEMENT OF IMINES [J].

ARMESTO, D ;

HORSPOOL, WM ;

LANGA, F ;

PEREZOSSORIO, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (08) :1039-1042

[2] THE AZA-DI-PI-METHANE REARRANGEMENT OF 1-ARYL-4,4-DIMETHYL-6,6-DIPHENYL-2-AZAHEXA-2,5-DIENES - THE INFLUENCE OF SUBSTITUENTS ON THE N-BENZYL GROUP [J].

ARMESTO, D ;

HORSPOOL, WM ;

LANGA, F .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1989, (07) :903-906

[3] A NOVEL AZA-DI-PI-METHANE REARRANGEMENT THE PHOTOREACTION OF 4,4-DIMETHYL-1,6,6-TRIPHENYL-2-AZA-HEXA-2,5-DIENE [J].

ARMESTO, D ;

MARTIN, JAF ;

PEREZOSSORIO, R ;

HORSPOOL, WM .

TETRAHEDRON LETTERS, 1982, 23 (20) :2149-2152

[4] STUDIES ON THE SCOPE OF THE AZA-DI-PI-METHANE REARRANGEMENT OF BETA,GAMMA-UNSATURATED IMINES [J].

ARMESTO, D ;

LANGA, F ;

MARTIN, JAF ;

PEREZOSSORIO, R ;

HORSPOOL, WM .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1987, (04) :743-746

[5] THE AZA-DI-PI-METHANE REARRANGEMENT OF O-ACETYL 2,2-DIMETHYL-4,4-DIPHENYLBUT-3-ENAL OXIME [J].

ARMESTO, D ;

HORSPOOL, WM ;

LANGA, F .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (24) :1874-1875

[6]

ARMESTO D, 1986, J CHEM RES-S, P46

[7]

ARMESTO D, IN PRESS J CHEM S P1

[8]

ARMESTO D, 1986, J CHEM RES M, P631

[9] PHOTOCHEMISTRY OF BETAALPHA-UNSATURATED CARBONYL-COMPOUNDS - 3,3-DIMETHYL-5,5-DIPHENYLPENT-4-EN-2-ONE AND "2,2-DIMETHYL-4,4-DIPHENYLBUT-3-ENAL [J].

PRATT, AC .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1973, (21) :2496-2499

[10] PHOTOCHEMISTRY OF THE CARBON-NITROGEN DOUBLE-BOND .2. AN INVESTIGATION OF THE 3-METHYLENEPROPAN-1-IMINE AND 3-OXOPROPAN-1-IMINE CHROMOPHORES [J].

PRATT, AC ;

ABDULMAJID, Q .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1987, (02) :359-364