BETA-CYCLOALTRIN - A CYCLOOLIGOSACCHARIDE CONSISTING OF 7 ALPHA(1-]4)-LINKED ALTROPYRANOSES

被引：33

作者：

FUJITA, K ^{[1
]}

SHIMADA, H ^{[1
]}

OHTA, K ^{[1
]}

NOGAMI, Y ^{[1
]}

NASU, K ^{[1
]}

KOGA, T ^{[1
]}

机构：

[1] DAIICHI COLL PHARMACEUT SCI,TOKYO,JAPAN

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 15期

关键词：

ALTROSE; BETA-CYCLOALTRIN; CYCLODEXTRINS; OLIGOSACCHARIDES;

D O I：

10.1002/anie.199516211

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A surprisingly simple approach—heating per‐2,3‐anhydro‐(2S)‐β‐cyclodextrin in water at reflux—provides the novel cyclooligosaccharide β‐cycloaltrin (1) in 73% yield. In this one‐step hydrolysis, ring opening results in the altro configuration in every sugar unit. The inclusion properties of 1 should be interesting. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：1621 / 1622

页数：2

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