INVESTIGATION OF POLY-(PARA-PHENYLENE) OBTAINED IN ELECTROCHEMICAL OXIDATION OF BENZENE IN THE BUPYCL-ALCL3 MELT AND IN ORGANIC-SOLVENTS WITH OLEUM

被引：10

作者：

GOLDENBERG, LM

PELEKH, AE

KRINICHNYI, VI

ROSHCHUPKINA, OS

ZUEVA, AF

LYUBOVSKAYA, RN

EFIMOV, ON

机构：

[1] Institute of Chemical Physics, USSR Academy of Sciences, Chernogolovka

来源：

SYNTHETIC METALS | 1991年 / 43卷 / 1-2期

关键词：

D O I：

10.1016/0379-6779(91)91240-B

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Poly-(p-phenylene) has been obtained in electrochemical oxidation of benzene in the BuPyCl-AlCl3 melt. The conductivity of the fresh film is 10-100 S/cm. Even when the film is stored in the dry inert atmosphere, its conductivity reduces. Poly-(p-phenylene) has been also obtained in electrooxidation of benzene with oleum or P2O5. Electrochemical properties and IR and ESR spectra have been investigated. The SEM data on the film morphology have been also discussed.

引用

页码：3071 / 3074

页数：4

共 9 条

[1] ELECTROPOLYMERIZATION OF BENZENE AND BIPHENYL IN ORGANIC MEDIA - INFLUENCE OF DIFFERENT PARAMETERS (SOLVENT, WATER, ACIDITY, SALT) ON THE FORMATION OF POLYPARAPHENYLENE FILMS (PPP) [J].