CRYSTAL AND MOLECULAR-STRUCTURE OF BISMUTH(III) 2,2-DIMETHYLPROPANOATE

被引：10

作者：

TROYANOV, SI ^{[1
]}

PISAREVSKY, AP ^{[1
]}

机构：

[1] MOSCOW MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 119899,RUSSIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 03期

关键词：

D O I：

10.1039/c39930000335

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

X-Ray investigations of single crystals of bismuth(III) 2,2-dimethylpropanoate (pivalate), obtained. by sublimation in vacuo, reveal its structure to consist of isolated tetrameric units [Bi(O2CCMe3)3]4; each of the twelve crystallographically inequivalent Bi atoms has practically the same coordination environment of nine O atoms at distances of 2.24-3.27 angstrom.

引用

页码：335 / 336

页数：2

共 7 条

[1]

DAVIDOVICH RL, 1988, KOORDINATS KHIM+, V14, P1011

[2]

Frenz B.A, 1978, COMPUTING CRYSTALLOG, P64

[3] MOLECULAR PRECURSORS OF BISMUTH OXIDES - BETA-DIKETONATES AND ALKOXIDES - MOLECULAR-STRUCTURE OF [BI2(MU-2,ETA-1-OC2H4OME)4(ETA-1-OC2H4OME)2]INFINITY AND OF BI(OSIPH3)3(THF)3 [J].

MASSIANI, MC ;

PAPIERNIK, R ;

HUBERTPFALZGRAF, LG ;

DARAN, JC .

POLYHEDRON, 1991, 10 (4-5) :437-445

[4]

PISAREVSKII AP, 1990, ZH NEORG KHIM+, V35, P1489

[5]

PISAREVSKII AP, 1992, ZH NEORG KHIM+, V37, P72

[6] CRYSTAL STRUCTURE OF BISMUTH(3) FORMATE [J].

STALHANDSKE, CI .

ACTA CHEMICA SCANDINAVICA, 1969, 23 (05) :1525-+

[7]

TROYANOV SI, 1991, KOORDINATS KHIM+, V17, P909

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