AN INFRARED SPECTROSCOPIC STUDY OF THE LOW-SPIN HIGH-SPIN TRANSITION IN FEXMN1-X(PHEN)2(NCS)2 - A COMPOSITION-INDUCED CHANGE IN THE ORDER OF THE SPIN-STATE TRANSITION

被引：11

作者：

VARMA, V

FERNANDES, JR

机构：

[1] Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 167卷 / 04期

关键词：

D O I：

10.1016/0009-2614(90)87184-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Infrared spectroscopy provides a valuable tool to investigate the spin-state transition in Fe(II) complexes of the type Fe(Phen)2(NCS)2. With progressive substitution of Fe by Mn, the first-order transition changes over to a second-order transition, with a high residual population of the high-spin state even at very low temperatures. © 1990.

引用

页码：367 / 370

页数：4

共 5 条

[1] FURTHER-STUDIES ON THE SPIN CROSSOVER PHENOMENON IN DI-ISOTHIOCYANATOBIS(1,10-PHENANTHROLINE)IRON(II) [J].