METAL ALKOXIDE CATALYSIS OF CATECHOLBORANE AND BORANE REDUCTIONS - MECHANISTIC STUDIES

被引：48

作者：

LINDSLEY, CW ^{[1
]}

DIMARE, M ^{[1
]}

机构：

[1] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 29期

关键词：

D O I：

10.1016/S0040-4039(00)77048-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Catalytic quantities of transition metal alkoxides such as Ti(OiPr)(4) have been found to accelerate dramatically the rate of catecholborane and BH3.THF reductions of ketones. Experiments suggest catalysis is achieved by the formation of alkoxyborohydrides.

引用

页码：5141 / 5144

页数：4

共 17 条

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