THE NONAAQUABISMUTH(III) CATION

被引：65

作者：

FRANK, W

REISS, GJ

SCHNEIDER, J

机构：

[1] Fachbereich Chemie, Universität Kaiserslautern, D-67653

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 21期

关键词：

AQUA COMPLEXES; BISMUTH COMPOUNDS; HYDROGEN BONDS;

D O I：

10.1002/anie.199524161

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first aqua complex of an element of group 15, namely the [Bi(H2O)9]3+ ion (shown on the right) in bismuth(III) trifluoromethanesulfonate enneahydrate, has been detected. Hence the last gap in the systematics of aqua complexes of main group metals has been closed. The central Bi3+ ion in the C3h‐symmetric coordination polyhedron–a tricapped trigonal prism—shows no recognizable stereochemical activity of the lone pair of electrons in the solid state. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2416 / 2417

页数：2

共 16 条

[1]

BAES CF, 1976, HYDROLYSIS CATIONS, P382

[2] ANTHRANILIC ACID-I, C7H7NO2, BY NEUTRON-DIFFRACTION [J].

BROWN, CJ ;

EHRENBERG, M .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 (MAR) :441-443

[3]

BURGESS J, 1988, IONS SOLUTION BASIC, P68

[4]

BURGESS J, 1987, COMP COORDINATION CH, V2, P305

[5]

Corey R.B., 1933, Z KRISTALLOGR, V84, P477

[6]

Cotton F.A., 1988, ADV INORG CHEM RAD, P420

[7]

Favas M. C., 1981, PROG INORG CHEM, V28, P309

[8] STRUCTURE AND STEREOCHEMISTRY IN F-BLOCK COMPLEXES OF HIGH COORDINATION-NUMBER .8. THE [M(UNIDENTATE)9] SYSTEM - CRYSTAL-STRUCTURES OF [M(OH2)9] [CF3SO3]3, M = LA, GD, LU, Y [J].

HARROWFIELD, JM ;

KEPERT, DL ;

PATRICK, JM ;

WHITE, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1983, 36 (03) :483-492

[9]

HOLLEMANWIBERG, 1985, LEHRBUCH ANORGANISCH, P694

[10] BISMUTH BASIC NITRATE [BI6(H2O)(NO3)O4(OH)4](NO3)5 [J].

LAZARINI, F .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1979, 35 (FEB) :448-450

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