PHOTOPHYSICS OF 10-SUBSTITUTED BIS[2-(9-ANTHRYL)ETHYL] GLUTARATES

被引：18

作者：

FOX, MA

BRITT, PF

机构：

[1] Department of Chemistry, University of Texas at Austin, Austin

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 16期

关键词：

D O I：

10.1021/j100379a037

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photophysical interactions between pendant anthryl groups in a family of bis[2-(9-anthryl)ethyl] glutarates have been characterized by steady-state and time-resolved fluorescence measurements. As the size of the 10-substituent increases, the rate of excimer formation decreases and the monomer-excimer equilibrium shifts toward the monomer. Thermodynamic and kinetic parameters influencing excimer formation are described. © 1990 American Chemical Society.

引用

页码：6351 / 6360

页数：10

共 37 条

[1] CONFORMATIONAL-ANALYSIS .130. MM2 - HYDROCARBON FORCE-FIELD UTILIZING V1 AND V2 TORSIONAL TERMS [J].