THE CRYSTAL AND MOLECULAR-STRUCTURE OF METHYL(CYCLOPENTANONE-THIOSEMICARBAZONATO)MERCURY(II)

被引：18

作者：

ZUKERMANSCHPECTOR, J ^{[1
]}

RODRIGUEZARGUELLES, MC ^{[1
]}

SUAREZ, MI ^{[1
]}

SANCHEZ, A ^{[1
]}

CASAS, JS ^{[1
]}

SORDO, J ^{[1
]}

机构：

[1] UNIV SANTIAGO COMPOSTELLA,DEPT QUIM INORGAN,E-15706 SANTIAGO,SPAIN

来源：

JOURNAL OF COORDINATION CHEMISTRY | 1991年 / 24卷 / 02期

关键词：

MERCURY(II); METHYLMERCURY(II); CYCLOPENTANONETHIOSEMICARBAZONE; X-RAY STRUCTURE;

D O I：

10.1080/00958979109409460

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of HgMe(L)(L = Cyclopentanonethiosemicarbazonato)has been determined. The compound, which crystallizes in the monoclinic space group P21/c with a = 8.973(2), b = 15.247(3), c = 7.511(2) A, p = 101.90(2)°, and Z = 4(R = 0.040, R’ = 0.041), is formed from molecules in which the thiosemicarbazonato anion forms a bond with mercury with the sulphur atom as well as a particularly strong secondary bond with nitrogen N(1). Molecules in the unit cell pack in pairs through weak hydrogen bonds. © 1991, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：177 / 181

页数：5

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