SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF OXOTRIMESITYLIRIDIUM(V)

被引：118

作者：

HAYMOTHERWELL, RS

WILKINSON, G

HUSSAINBATES, B

HURSTHOUSE, MB

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,JOHNSON MATTHEY LAB,LONDON SW7 2AY,ENGLAND

[2] UNIV WALES CARDIFF,DEPT CHEM & APPL CHEM,CARDIFF CF1 3TB,WALES

来源：

POLYHEDRON | 1993年 / 12卷 / 16期

关键词：

D O I：

10.1016/S0277-5387(00)81474-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interaction of trimesityliridium(III) with trimethylamine oxide gives quantitative yields of the green iridium(V) complex Ir(O)(mes)3, whose X-ray crystal structure has been determined. The oxo compound is also obtained by interaction of dioxygen with Ir(mes)3 and Ir(mes)4. A similar oxo species has also been obtained from Ir(2,6-Me2C6H3)4. The molecular structure of Ir(O)(mes)3 is distorted tetrahedral with Ir=O and Ir-C bond lengths of 1.725(9) and 1.989-2.034(13) angstrom, respectively.

引用

页码：2009 / 2012

页数：4

共 10 条

[1] OXIDATION OF HEXAAQUAIRIDIUM(III) AND RELATED STUDIES - PREPARATION AND PROPERTIES OF IRIDIUM(III), IRIDIUM(IV), AND IRIDIUM(V) DIMERS AS AQUA IONS [J].