ELECTRONIC-STRUCTURE AND SPECTROSCOPIC PROPERTIES OF COPPER CATECHOLATE COMPLEXES WITH INTERLIGAND CHARGE-TRANSFER BEHAVIOR

被引：18

作者：

BENEDIX, R ^{[1
]}

VOGLER, A ^{[1
]}

机构：

[1] UNIV REGENSBURG,INST ANORGAN CHEM,W-8400 REGENSBURG,GERMANY

来源：

INORGANICA CHIMICA ACTA | 1993年 / 204卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)82924-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structural and spectroscopic properties of copper catecholate complexes with nitrogen ligands of the alpha-diimine type are studied by qualitative MO considerations. The characteristic feature of these donor acceptor systems is an interligand charge-transfer from the catecholate donor to the alpha-diimine acceptor site. The dependence of the interligand charge-transfer absorption band on the energies of the acceptor and the donor levels as well as on the solvent polarity is discussed.

引用

页码：189 / 193

页数：5

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