RESOLUTION OF RACEMIC EPSILON-LACTONES

被引:17
作者
FELLOUS, R
LIZZANICUVELIER, L
LOISEAU, MA
SASSY, E
机构
[1] Laboratoire de Chimie des Arômes, Université de Nice Sophia-Antipolis, 06108 Nice Cédex 2, Parc Valrose
关键词
D O I
10.1016/S0957-4166(00)86202-3
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Kinetic resolution of racemic epsilon-lactones by Pig Liver Esterase give optically active R (+) epsilon-lactones. When alkyl group is higher than propyl, Horse Liver Esterase leads to the destruction of the opposite enantiomer. Enantiomeric excess is easily evaluated by G.C. on a chiral stationary phase.
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页码:343 / 346
页数:4
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