SYNTHESIS AND CHARACTERIZATION OF 2-FERROCENYL-4,4,5,5-TETRAMETHYL-2-IMIDAZOLIN-1-OXYL 3-OXIDE AND ITS CT-COMPLEX WITH DDQ

被引：32

作者：

NAKAMURA, Y ^{[1
]}

KOGA, N ^{[1
]}

IWAMURA, H ^{[1
]}

机构：

[1] UNIV TOKYO, FAC SCI, DEPT CHEM, BUNKYO KU, TOKYO 113, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 01期

关键词：

D O I：

10.1246/cl.1991.69

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A ferrocene derivative carrying a nitronyl-nitroxide radical was synthesized and its CT salt with DDQ was prepared. There are two S = 1/2 spins, ferrocenium ion and nitronyl-nitroxide radical, on the cationic part of the CT-salt. From the temperature dependence of magnetic susceptibility data it is concluded that the interaction between them is antiferromagnetic (2J almost-equal-to-50 cm-1).

引用

页码：69 / 72

页数：4

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