PORPHYRIN-CATALYZED DEGRADATION OF CHLORINATED PHENOLS AND NITROSUBSTITUTED TOLUENES

被引：14

作者：

HASAN, S

CHO, JG

SUBLETTE, KL

PAK, D

MAULE, A

机构：

[1] UNIV TULSA,CTR ENVIRONM RES & TECHNOL,600 S COLL AVE,TULSA,OK 74104

[2] MICHIGAN STATE UNIV,E LANSING,MI 48824

[3] PUBL HLTH LAB SERV,DIV BIOTECHNOL,SALISBURY,ENGLAND

来源：

JOURNAL OF BIOTECHNOLOGY | 1992年 / 24卷 / 02期

关键词：

PORPHYRIN; MUNITION; TRICHLOROPHENOL; NITROBODY; BIOMIMETIC;

D O I：

10.1016/0168-1656(92)90123-Q

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

Porphyrin-metal complexes have been used to catalyze the reduction of nitro-substituted toluenes to the corresponding amines as a preparatory step to enhance biodegradability. Dithiothreitol was used as a reducing agent. Complete conversion of 2-nitro-, 4-nitro- and 2,4-dinitrotoluene was observed with transient accumulation of nitroso intermediates. 2,4,6-Trichlorophenol has been shown to be oxidized by t-butyl hydroperoxide in a reaction catalyzed by an iron-centered porphyrin. All organic chlorine was converted to chloride ion.

引用

页码：195 / 201

页数：7

共 11 条

[1] IDENTIFICATION OF HIGH-VALENT FLUOROIRON PORPHYRIN INTERMEDIATES ASSOCIATED WITH THE ELECTROCATALYTIC FUNCTIONALIZATION OF HYDROCARBONS [J].