OXIDATIVE CONVERSION OF ALDOXIMES INTO CARBOXYLIC-ACID ESTERS

被引：23

作者：

SAID, SB ^{[1
]}

SKARZEWSKI, J ^{[1
]}

MLOCHOWSKI, J ^{[1
]}

机构：

[1] WROCLAW TECH UNIV,INST ORGAN & PHYS CHEM,WYB WYSPIANSKIEGO 27,PL-50370 WROCLAW,POLAND

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 13期

关键词：

D O I：

10.1080/00397919208021316

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aromatic and aliphatic aldoximes or their O-methyl ethers can be efficiently converted into the corresponding carboxylic acid esters by treatment with an alcoholic solution of 30% hydrogen peroxide in the Presence of catalytic amounts of 2-nitrobenzeneseleninic acid. Primary alcohols give excellent to good yields, secondary ones - good to moderate, but with tertiary alcohols no esterification is obserwed.

引用

页码：1851 / 1862

页数：12

共 21 条

[1]

ALNEIRABEYEH M, 1990, TETRAHEDRON LETT, V31, P2273

[2]

ARNDT F, 1953, J CHEM SOC, P5

[3]

BARDY OL, 1924, J CHEM SOC, P551

[4] OXIDATION AND CHARACTERIZATION OF ALPHA,ALPHA'-DICHLORO-PARA-XYLENE [J].

BENGELSDORF, IS .

JOURNAL OF ORGANIC CHEMISTRY, 1958, 23 (02) :242-246

[5] Free radicals and radical stability Part XII Fluorotriphenylmethyl and the reactivity of halogen substituents in free radicals [J].

Bowden, ST ;

Watkins, TF .

JOURNAL OF THE CHEMICAL SOCIETY, 1940, :1249-1257

[6] LESS FAMILIAR REACTIONS OF OXIMES [J].

FREEMAN, JP .

CHEMICAL REVIEWS, 1973, 73 (04) :283-292

[7]

Henry P M, 1977, CHEM DOUBLE BON 2 SA, P1067

[8]

HERZIG J, 1912, MONATSH CHEM, V33, P846

[9]

JARGLIS P, 1988, SYNTHESIS-STUTTGART, P790

[10] Information on trimethyl gallus aldehydes. Synthesis of methyl-sinapinic acid. [J].

Mauthner, F .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1908, 41 :2530-2533

← 1 2 3 →