THE 1ST UNDECARUTHENIUM HYDRIDO CARBONYL ANION - SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [RU11H(CO)27]3-

被引：17

作者：

BAILEY, PJ ^{[1
]}

BESWICK, MA ^{[1
]}

JOHNSON, BFG ^{[1
]}

LEWIS, J ^{[1
]}

RAITHBY, PR ^{[1
]}

DE ARELLANO, MCR ^{[1
]}

机构：

[1] UNIV CAMBRIDGE, DEPT CHEM, LENSFIELD RD, CAMBRIDGE CB2 1EW, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 21期

关键词：

D O I：

10.1039/dt9920003159

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cluster trianion [Ru11H(CO)27]3- has been obtained from the thermolysis of [Ru3(CO)12] in a methanol-water mixture; an X-ray structure analysis of the [NEt3(CH2Ph)]+ salt shows that the metal core in the anion is a fragment of hexagonal close packing, which may be described alternatively as the condensation between two octahedra and two trigonal bipyramids sharing common triangular faces.

引用

页码：3159 / 3160

页数：2

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