REACTIONS OF THE DIRHENIUM(II) COMPLEXES RE2X4(DPPM)2 (X = CL, BR - DPPM = PH2PCH2PPH2) WITH ISOCYANIDES .5. MIXED CARBONYL ISOCYANIDE AND CARBONYL ISOCYANIDE NITRILE COMPLEXES OF STOICHIOMETRY [RE2CL3(DPPM)2(CO)(CNR)(L)]PF6 (R = TERT-BU, XYL (XYLYL) - L = TERT-BUNC, XYLNC, MECN, ETCN) - STRUCTURAL CHARACTERIZATION OF THE CATION [CL2(CO)RE(MU-DPPM)2RECL(CN-TERT-BU)2]+L

被引：19

作者：

FANWICK, PE ^{[1
]}

PRICE, AC ^{[1
]}

WALTON, RA ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

INORGANIC CHEMISTRY | 1988年 / 27卷 / 15期

关键词：

D O I：

10.1021/ic00288a010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：2601 / 2607

页数：7

共 21 条

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[2] REACTIONS OF THE DIRHENIUM(II) COMPLEXES RE2X4(DPPM)2(X = CL OR BR DPPM = PH2PCH2PPH2) WITH ISOCYANIDES .4. ISOMERISM IN MIXED CARBONYL-ISOCYANIDE COMPLEXES OF STOICHIOMETRY [RE2CL3(DPPM)2(CO)2(CNR)]N+(N = 0 OR 1) AND [RE2CL3(DPPM)2(CO)(CNR)2]+(R = T-BU OR XYLYL), WHICH POSESS EDGE-SHARED BIOCTAHEDRAL STRUCTURESN
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[3] REACTIONS OF THE DIRHENIUM(II) COMPLEXES RE2CL4(PH2PCH2PPH2)2 OR RE2BR4(PH2PCH2PPH2)2 WITH ISOCYANIDES .3. DINUCLEAR SPECIES CONTAINING 2 OR 3 ISOCYANIDE LIGANDS
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[4] REACTIONS OF THE DIRHENIUM(II) COMPLEXES [RE2X4(DPPM)2] (X = CL OR BR, DPPM = PH2PCH2PPH2) WITH ISOCYANIDES .2. THE A-FRAME-LIKE MONOISOCYANIDE SPECIES [RE2(MU-X)(MU-DPPM)2X3(CNR)]N+ (R = ME, BUT, OR C6H3ME2-2,6,N = 0 OR 1)
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[5] STRUCTURAL CHARACTERIZATION OF THE TRIPLY BONDED DIRHENIUM(II) COMPLEXES RE2CL4(MU-PH2PCH2PPH2)2 AND ALPHA-RE2CL4(ME2P(CH2)2PME2)
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[6] UNUSUAL REACTIVITY ASSOCIATED WITH THE TRIPLY BONDED RE-(2)4+ CORE - FACILE REACTION OF RE2CL4(PH2PCH2PPH2)2 WITH NITRILES TO AFFORD THE CATIONS [RE2CL3(PH2PCH2PPH2)2(NCR)2]+
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[7] MULTIPLY BONDED DIMETAL COMPLEXES CONTAINING BIS(DIPHENYLPHOSPHINO)METHANE BRIDGES - COMPLEXES POSSESSING RHENIUM-RHENIUM DOUBLE-BONDS AND A TUNGSTEN-TUNGSTEN SINGLE BOND
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[8] THE HYDRATED METHOXIDE ION, CH3O-.6H2O
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[9] Cotton F. A., 1982, MULTIPLE BONDS METAL
[10] REACTIONS OF THE DICARBONYL COMPLEX RE2CL4(DPPM)2(CO)2 WITH NITRILES AND ISOCYANIDES - SYNTHESIS OF [RE2CL3(DPPM)2(CO)2L]N+ (N = 0, 1 - L = RCN, RNC) AND THE STRUCTURAL CHARACTERIZATION OF [RE2CL3(DPPM)2(CO)2(NCC2H5)]PF6
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