DYNAMIC AND STATIC LATTICE EFFECTS IN TETRACHLOROFERRATE(II) SALTS - THEIR INFLUENCE UPON MOSSBAUER QUADRUPOLE SPLITTINGS

被引：5

作者：

SLADE, E

HOULTON, A

SILVER, J

EVANS, DJ

LEIGH, GJ

机构：

[1] UNIV ESSEX,DEPT CHEM & BIOL CHEM,WIVENHOE PK,COLCHESTER CO4 3SQ,ESSEX,ENGLAND

[2] UNIV SUSSEX,AFRC,INST PLANT SCI RES,NITROGEN FIXAT LAB,BRIGHTON BN1 9RQ,E SUSSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 08期

关键词：

D O I：

10.1039/dt9930001217

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Spectroscopic data, particularly Fe-57 Mossbauer, and X-ray powder diffraction data are presented for a series of salts [NR4]2[FeCl4] and for doped materials of [NMe4]2[FeCl4] and [NMe4]2[CoCl4] in different ratios. The effect of the cation on the electronic environment of the iron is discussed in terms of direct charge effects and lattice dynamics.

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页码：1217 / 1221

页数：5

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