ELECTRODEPOSITION OF THIN-FILMS OF NICKEL-IRON .2. MODELING

被引:113
作者
GRANDE, WC
TALBOT, JB
机构
[1] Department of AMES/Chemical Engineering, University of California, San Diego, La Jolla
关键词
D O I
10.1149/1.2056141
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
A mathematical model is developed to simulate the electrodeposition of the nickel-iron alloy from simple sulfate solutions. Equilibrium calculations indicate the importance of the metal monohydroxide species in the codeposition mechanism. A one-dimensional diffusion model of the codeposition is developed and agrees well with experimental results for different bath compositions and operating conditions. The sensitivity of the model is evaluated and a mechanism for the anomalous codeposition of nickel-iron is proposed.
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收藏
页码:675 / 681
页数:7
相关论文
共 35 条
[1]   ELECTRODEPOSITION OF NICKEL-IRON ALLOYS .1. EFFECT OF AGITATION [J].
ANDRICACOS, PC ;
ARANA, C ;
TABIB, J ;
DUKOVIC, J ;
ROMANKIW, LT .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (05) :1336-1340
[2]  
Baes CF., 1976, HYDROLYSIS CATIONS
[3]  
Brenner A, 1963, ELECTRODEPOSITION AL, V1
[4]  
COTTON FA, 1975, ADV INORGANIC CHEM
[5]   ANOMALOUS CODEPOSITION OF IRON-NICKEL ALLOYS [J].
DAHMS, H ;
CROLL, IM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1965, 112 (08) :771-&
[6]   THE RELATIVE ELECTROCATALYTIC ACTIVITY OF NOBLE METALS IN THE OXIDATION OF ETHYLENE [J].
DAHMS, H ;
BOCKRIS, JO .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1964, 111 (06) :728-736
[7]  
DELIGIANNI H, 1990, ELECTROCHEMICAL SOC, P423
[8]  
DELIGIANNI H, EL SOC EXT ABSTR, P498
[9]   ANOMALOUS ELECTRODEPOSITION OF NICKEL-IRON [J].
GANGASINGH, D ;
TALBOT, JB .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (12) :3605-3611
[10]  
GANGASINGH D, 1988, THESIS U CALIFORNIA