SYNTHESIS AND CRYSTAL-STRUCTURE OF 10-COORDINATE [TH(C5H5NO)6(NO3)2](NO3)2 (C5H5NO=2-(1H)-PYRIDONE)

被引：9

作者：

GOODGAME, DML

NEWNHAM, S

OMAHONEY, CA

WILLIAMS, DJ

机构：

[1] Chemistry Department, Imperial College of Science, Technology and Medicine, London

来源：

POLYHEDRON | 1990年 / 9卷 / 04期

关键词：

D O I：

10.1016/S0277-5387(00)86223-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Attempts to prepare polynuclear, heterometallic CuII/ThIV complexes with 2- pyridone (= L) bridges, analogous to those formed by CuII/DyIII and CuII/GdIII gave instead [ThL6(NO3)2](NO3)2, which has been characterized by X-ray diffraction. The Th atom is 10-coordinate with two bidentate nitrates and the six pyridone oxygen atoms forming a distorted bicapped square antiprism. © 1990.

引用

页码：491 / 494

页数：4

共 5 条

[1] CRYSTAL-STRUCTURE OF TETRAPOTASSIUM TETRAOXALATOTHORIUM(IV) TETRAHYDRATE, K4TH(C2O4)4.4H2O [J].