TI COMPOUNDS WITH FULVALENE BRIDGES - STRUCTURE OF [CPTIBR]2(C10H8, O).TOLUENE

被引:7
作者
WOHRLE, T [1 ]
THEWALT, U [1 ]
机构
[1] UNIV ULM,SEKT RONTGEN & ELEKTRONENBEUGUNG,ALBERT EINSTEIN ALLEE 11,W-7900 ULM,GERMANY
关键词
D O I
10.1016/0022-328X(93)80271-C
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The green Ti(IV) compounds which are obtained by treating titanocene with HCl or Br2 form, on reaction with MeLi and subsequent hydrolysis, the following compounds containing fulvalene bridges: [CpTiCl]2(C10H8,O) (3(Cl)) and [CpTiBr]2(C10H8,O) (3(Br)). Their structures have been determined by X-ray crystallography.
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页码:45 / 50
页数:6
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