OXOVANADIUM-INDUCED OXIDATIVE DESILYLATION OF ALLYLIC AND BENZYLIC SILANES

被引：33

作者：

FUJII, T ^{[1
]}

HIRAO, T ^{[1
]}

OHSHIRO, Y ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 565,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 35期

关键词：

D O I：

10.1016/S0040-4039(00)73892-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cinnamyltrimethylsilane underwent desilylation via one-electron oxidation with VO(OEt)Cl2, which was applied to the cross-coupling with the less oxidizable allylic silanes to give the corresponding 1,5-hexadienes. Chlorination or aromatization based on desilylation was observed on treatment of benzyltrimethylsilane or 3-ethoxycarbonyl-2-methyl-5-trimethylsilyl-5-phenyl-4,5-dihydrofuran with VO(OEt)Cl2-Me3SiOTf, respectively.

引用

页码：5601 / 5604

页数：4

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