NEW ET-BASED ORGANIC SUPERCONDUCTORS WITH THE ORGANOMETALLIC ANION CU(CF3)(4)(-)

被引：9

作者：

GEISER, U

SCHLUETER, JA

CARLSON, KD

WILLIAMS, JM

WANG, HH

KWOK, WK

WELP, U

FENDRICH, JA

DUDEK, JD

ACHENBACH, CA

KOMOSA, AS

KEANE, PM

NAUMANN, D

ROY, T

SCHIRBER, JE

BAYLESS, WR

REN, J

WHANGBO, MH

机构：

[1] ARGONNE NATL LAB,DIV MAT SCI,ARGONNE,IL 60439

[2] UNIV COLOGNE,INST ANORGAN CHEM,D-50939 COLOGNE,GERMANY

[3] SANDIA NATL LABS,ALBUQUERQUE,NM 87185

[4] N CAROLINA STATE UNIV,DEPT CHEM,RALEIGH,NC 27695

来源：

SYNTHETIC METALS | 1995年 / 70卷 / 1-3期

关键词：

D O I：

10.1016/0379-6779(94)02775-T

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Electrocrystallization of bis(ethylenedithio)tetrathiafulvalene (ET) with (PNP)Cu(CF3)(4) in 1,1,2-trichloroethane (TCE) results in two new superconductors, kappa(L)-(ET)(2)Cu(CF3)(4)(TCE), 1, with T-c = 4.0 K, and kappa(H)-(ET)(2)Cu(CF3)(4).(TCE)(x), 2, with T-c = 9.2 K. I forms well-developed plate-like crystals whose structure was determined by X-ray crystallography. Its band electronic structure is reported. The kappa(H)-phase forms long, thin needle bundles.

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收藏

页码：1105 / 1108

页数：4

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