SYNTHESIS AND CHARACTERIZATION OF RHENIUM METALLOCARBOXYLATES

被引：39

作者：

GIBSON, DH

MEHTA, JM

YE, M

RICHARDSON, JF

MASHUTA, MS

机构：

[1] Department of Chemistry, University of Louisville, Louisville

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 04期

关键词：

D O I：

10.1021/om00016a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of a new metallocarboxylic acid, Cp*Re(CO)(NO)COOH (2), with Ph3SnCl and Re(CO)4-(PPh3)(F-BF3) have provided the corresponding CO2-bridged complexes Cp*Re(CO)(NO)(CO2)SnPh3 (3) and Cp*Re(CO)(NO)(CO2)Re(CO)3(PPh3) (4), which have been structurally characterized. Complexes 3 and 4 exhibit different types of mu2-eta3 bonding of the bridging CO2 ligand which can be correlated with the IR and C-13 NMR spectral properties of the compounds.

引用

页码：1070 / 1072

页数：3

共 38 条

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