STRUCTURE OF DICHLORO[(Z)-2-CHLORO-2-P-POLYLVINYL](P-METHOXYPHENYL)TELLURIUM(IV)

被引：22

作者：

ZUKERMANSCHPECTOR, J ^{[1
]}

CASTELLANO, EE ^{[1
]}

OLIVA, G ^{[1
]}

COMASSETO, JV ^{[1
]}

STEFANI, HA ^{[1
]}

机构：

[1] UNIV SAO PAULO,INST QUIM,BR-01498 SAO PAULO,SP,BRAZIL

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1991年 / 47卷

关键词：

D O I：

10.1107/S0108270190012288

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[TeCl2(C9H8Cl)(C7H7O)], M(r) = 457.26, orthorhombic, Pbcn, a = 18.829 (3), b = 8.809 (3), c = 20.969 (3) angstrom, V = 3478 (2) angstrom 3, Z = 8, D(x) = 1.747 g cm-3, lambda(Mo K-alpha) = 0.71073 angstrom, mu = 21.75 cm-1, F(000) = 1776, T = 296 K, final R = 0.034 for 1958 independent observed reflections. The Te(IV) ion is in a trigonal bipyramidal configuration with the lone pair of electrons at one of the equatorial positions. Distances and angles are: Te-Cl = 2.478 (2), 2.521 (2); Te-C = 2.085 (6), 2.117 (5) (aryl) angstrom; Cl-Te-Cl = 177.65 (6); Cl-Te-C = 90.8 (2), 90.2 (1), 86.8 (2), 90.1 (1); C-Te-C = 94.1 (2)-degrees.

引用

页码：960 / 962

页数：3

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