METAL-ASSISTED ORGANIZATION RATHER THAN PREORGANIZATION FOR THE DESIGN OF MACROCYCLIC HOSTS

被引:39
作者
KOBUKE, Y [1 ]
SUMIDA, Y [1 ]
HAYASHI, M [1 ]
OGOSHI, H [1 ]
机构
[1] KYOTO UNIV,FAC ENGN,DEPT SYNTHET CHEM,KYOTO 606,JAPAN
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 11期
关键词
D O I
10.1002/anie.199114961
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Boric acid initiates the formation of coronand 1 from 2, providing the framework necessary for the strong complexation of alkali metal ions. This approach to the synthesis of the macrocyclic host allows a greater flexibility than the standard preorganization method. A bicyclic coronand is also obtained by this strategy. M = K, Na.
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页码:1496 / 1498
页数:3
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