PHENOL RECOVERY WITH SLM USING CYANEX-923

被引:22
作者
GAREA, A [1 ]
URTIAGA, AM [1 ]
ORTIZ, MI [1 ]
ALONSO, AI [1 ]
IRABIEN, JA [1 ]
机构
[1] UNIV CANTABRIA,ESCUELA POLITECN SUPER INGN,DEPT QUIM,CALLE SEVILLA 6,E-39001 SANTANDER,SPAIN
关键词
SLM; HOLLOW FIBER; PHENOL; CYANEX-923;
D O I
10.1080/00986449308936126
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The study of the phenol separation-concentration process with the hollow fiber supported liquid membrane technology has been performed. Mixtures of kerosene and CYANEX 923 were used as liquid membrane. The extractant CYANEX 923 is characterized by a high phenol selectivity and an extremely low solubility in the aqueous phase. The introduction of CYANEX 923 in the membrane composition decreases the extractant losses from the pores of the support. The phenol separation and simultaneous concentration process has been checked. The influences of the initial concentration of phenol in the feed solution and sodium hydroxide in the stripping phase and the membrane composition on the separation rate have been investigated in a single-pass mode. The analysis of the membrane composition influence has been performed according to the steady-state mass transfer conservation equation and the associated boundary conditions, leading to the mass transfer parameters of the process.
引用
收藏
页码:85 / 97
页数:13
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