ON IRRADIATION OF POLY(VINYL CHLORIDE)

被引：31

作者：

SALOVEY, R

LUONGO, JP

YAGER, WA

机构：

[1] Bell Telephone Laboratories, Murray Hill, New Jersey

来源：

MACROMOLECULES | 1969年 / 2卷 / 02期

关键词：

D O I：

10.1021/ma60008a018

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Irradiated polyvinyl chloride) was examined on postirradiation storage by electron spin resonance and ultraviolet-visible absorption spectroscopy. In the absence of reactive additives, a stable concentration of polyenyl free radicals and an increase in the concentration of conjugated double bonds are observed. A radiation-induced radical chain dehydrochlorination is inferred. The presence of reactive additives suppresses the formation of polyenyl radicals and optical absorption. © 1969, American Chemical Society. All rights reserved.

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页码：198 / &

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