HYDROTHERMAL SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF A REDUCED, ARSENIC RICH HETEROPOLYANION, NA4[MO4AS6O20(OH)2].9H2O

被引：24

作者：

KHAN, MI ^{[1
]}

CHEN, Q ^{[1
]}

ZUBIETA, J ^{[1
]}

机构：

[1] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 04期

关键词：

D O I：

10.1039/c39930000356

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrothermal reaction of Na3MoO4.2H2O, Mo metal, MnO3, H5AS3O10, NaCl and H2O in the mole ratio 6: 6: 6: 3: 10: 166 for 110 h at 180-degrees-C yielded orange crystals of the sodium salt of the arsenic-rich Mo(V)-As(III) polyanion cluster, Na4[Mo4As6O20(OH)2].9H2O.

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页码：356 / 357

页数：2

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