SYNTHESIS OF OLEYL OLEATE AS A JOJOBA OIL ANALOG

被引：34

作者：

SANCHEZ, N

MARTINEZ, M

ARACIL, J

CORMA, A

机构：

[1] UNIV COMPLUTENSE,DEPT INGN QUIM,E-28040 MADRID,SPAIN

[2] UNIV POLITECN VALENCIA,CSIC,INST TECNOL QUIM,E-46071 VALENCIA,SPAIN

来源：

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 1992年 / 69卷 / 11期

关键词：

ESTERIFICATION; FACTORIAL DESIGN; JOJOBA OIL; WAX ESTER; ZEOLITE;

D O I：

10.1007/BF02541053

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Synthesis of a wax ester analog of jojoba oil was accomplished from oleic acid and oleyl alcohol with a zeolite as catalyst. A full 2(3) factorial design at two levels has been used in the synthesis. The variables selected were temperature, reduced pressure and initial catalyst concentration. The most important variable within the range studied was temperature. Reduced pressure had a negative influence, and initial catalyst concentration showed a positive influence on the process. A response equation has been determined for the yield of ester. The properties of the synthesized product are similar to those of natural jojoba oil.

引用

页码：1150 / 1153

页数：4

共 10 条

[1] FORMATION OF A JOJOBA OIL ANALOG BY ESTERIFICATION OF OLEIC-ACID USING ZEOLITES AS CATALYST
ARACIL, J
MARTINEZ, M
SANCHEZ, N
CORMA, A
[J]. ZEOLITES, 1992, 12 (03): : 233 - 236
[2] ARACIL J, 1992, IND ENG CHEM RES, V31, P1988
[3] ARACIL J, IN PRESS CAN J CHEM
[4] BOX GEP, 1976, STATISTICS EXPT
[5] Daniel C., 1959, TECHNOMETRICS, V1, P311, DOI DOI 10.1080/00401706.1959.10489866
[6] MARCH J, 1985, ADV ORGANIC CHEM
[7] SYNTHESIS OF ESTERS OF HIGH MOLECULAR-WEIGHT - AN ANALOG OF JOJOBA OIL - A STATISTICAL APPROACH
MARTINEZ, M
TORRANO, E
ARACIL, J
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1988, 27 (11) : 2179 - 2182
[8] MEFFERT A, 1984, J AM OIL CHEM SOC, V61, P255
[9] MEFFERT A, 1988, J AM OIL CHEM SOC, V65, P25
[10] 1938, TEST SIMMODSIA CHINE

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