THIOPHENOL PROTECTING GROUPS FOR THE PALLADIUM-CATALYZED HECK REACTION - EFFICIENT SYNTHESES OF CONJUGATED ARYLTHIOLS

被引：66

作者：

HSUNG, RP

BABCOCK, JR

CHIDSEY, CED

SITA, LR

机构：

[1] UNIV CHICAGO,DEPT CHEM,SEARLE CHEM LAB,CHICAGO,IL 60637

[2] STANFORD UNIV,DEPT CHEM,PALO ALTO,CA 94305

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 26期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0040-4039(95)00861-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A variety of S-thiophenol protecting groups have been evaluated for the Heck reaction. Of these, the S-acetyl group appears to be the best suited for facile removal under mild conditions to provide the corresponding free thiols in high yields.

引用

页码：4525 / 4528

页数：4

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