CARBON-MONOXIDE INDUCED ALLYL COUPLING FROM MO2(MU-2-ETA-3-ALLYL)2(ETA-3-ALLYL)2 YIELDING THE LABILE COMPLEX MO(CO)4(ETA-4-1,5-HEXADIENE)

被引：13

作者：

BLAU, RJ ^{[1
]}

SIRIWARDANE, U ^{[1
]}

机构：

[1] SO METHODIST UNIV,DEPT CHEM,DALLAS,TX 75275

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 05期

关键词：

D O I：

10.1021/om00051a065

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Carbon monoxide induces the reductive elimination of two pairs of allylic ligands from Mo2(mu-2-eta-3-allyl)2(eta-3-allyl)2 with the accompanying cleavage of the Mo-Mo quadruple bond. Mo(eta-4-1,5-hexadiene)(CO)4 is obtained from the reaction of 8 equiv of CO with Mo2(mu-2-eta-3-allyl)2(eta-3-allyl)2. Structural data for and the reactivity of Mo(eta-4-1,5-hexadiene)(CO)4 suggest that 1,5-hexadiene is bound very weakly to molybdenum.

引用

页码：1627 / 1630

页数：4

共 24 条

[1]

ATWOOD JD, 1985, INORGANIC ORGANOMETA, P54

[2] POLYMERISATION OF VINYL MONOMERS BY TRANSITION-METAL ALLYL COMPOUNDS .I. [J].