PHOTOLYSIS OF DIOXIRANES IN THE PRESENCE OF A NITROXIDE RADICAL SCAVENGER - THE INTERMEDIACY OF RADICAL-ANION AND DIYL SPECIES IN THE PRODUCTION AND TRAPPING OF METHYL AND TRIFLUOROMETHYL RADICALS

被引：22

作者：

ADAM, W

BOTTLE, SE

MELLO, R

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 11期

关键词：

D O I：

10.1039/c39910000771

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electron transfer between dioxiranes 1 and nitroxide 2 affords the dioxirane radical anion-oxoammonium cation pair, which generates methyl radicals that are trapped by the nitroxide.

引用

页码：771 / 773

页数：3

共 8 条

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