KINETICS OF CURING REACTION OF EPOXIDE CATALYZED BY TERTIARY AMINE

被引：41

作者：

HAN, JL

HSIEH, KH

CHIU, WY

机构：

[1] NATL TAIWAN UNIV,INST MAT SCI & ENGN,TAIPEI 106,TAIWAN

[2] NATL TAIWAN UNIV,DEPT CHEM ENGN,TAIPEI 106,TAIWAN

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 1993年 / 50卷 / 06期

关键词：

D O I：

10.1002/app.1993.070500618

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The kinetic study of the curing reaction of epoxide catalyzed by tertiary amine was carried out through thermal analysis of the reaction by differential scanning calorimetry (DSC). Using infrared spectroscopy (IR) and neutron magnetic reasonance (NMR) analysis, a reaction mechanism for this reaction was proposed. The reaction proceeded to anionic polymerization. An autocatalytic reaction was induced at high concentration of the tertiary amine catalyst. (C) 1993 John Wiley & Sons, Inc.

引用

页码：1099 / 1106

页数：8

共 22 条

[1] POLYMERIZATION OF PARA-CRESYL GLYCIDYL ETHER INDUCED BY BENZYLDIMETHYLAMINE [J].