ATTRACTIVE STERIC INTERACTIONS WITHIN MOLECULES - THE MASKING OF EFFECTS IN META-DISUBSTITUTED BENZENES BY BUTTRESSED REPULSIVE INTERACTIONS

被引：16

作者：

ANDERSON, JE ^{[1
]}

BRUCAPDEVILLE, V ^{[1
]}

KIRSCH, PA ^{[1
]}

LOMAS, JS ^{[1
]}

机构：

[1] UNIV PARIS 07,INST TOPOL & DYNAM SYST,CNRS,URA 34,F-75005 PARIS,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 09期

关键词：

D O I：

10.1039/c39940001077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The attractive steric interaction between the groups in a sidechain to a benzene ring and a meta-substituent is usually more than offset by the repulsive interaction of the sidechain with the ortho-hydrogen atom which is buttressed by the meta-substituent.

引用

页码：1077 / 1078

页数：2

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