THE SYNTHESIS AND SINGLE-CRYSTAL X-RAY STRUCTURE OF THE FIRST EXAMPLE OF A TRIDENTATE, DI-ORTHOMETALLATED TRIPHENYL PHOSPHITE COMPLEX

被引：10

作者：

BEDFORD, RB ^{[1
]}

CHALONER, PA ^{[1
]}

HITCHCOCK, PB ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 20期

关键词：

D O I：

10.1039/c39950002049

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [Ir(cod)(py)(2)][PF6] with triphenyl phosphite leads to the previously reported complex [Ir(cod){P(OC6H4)(OPh)(2)}{P(OPh)(3)}], but reaction of [Ir(cod){P(OPh)(3)}Cl] with methyllithium and subsequent treatment with methanol yields the tridentate di-orthometallated complex [IrH(cod){P(OC6H4)(2)(OPh)}].

引用

页码：2049 / 2050

页数：2

共 8 条

[1]

Bedford R. B., UNPUB

[2]

CHALONER PA, 1993, LATIN AM INORGANIC M, P254

[3]

DEWAAL DJA, 1987, S AFR J CHEM, V40, P193

[4]

HAINES LM, 1970, J ORGANOMET CHEM, V25, pC83

[5] STRUCTURE OF METALLATED IRIDIUM COMPLEX [(C8H12)IR[P(OC6H3ME)(OC6H4ME)2][P(OCH2)3CME]] [J].

LAING, M ;

NOLTE, MJ ;

SINGLETON, E ;

VANDERSTOK, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 146 (01) :77-86

[6]

LEIGH GJ, 1992, COMPREHENSIVE ORGANO, V5, P582

[7] TRIS(TRIPHENYLPHOSPHINE)METHYLIRIDIUM(I) - SYNTHESIS, CHARACTERIZATION, AND THERMAL-DECOMPOSITION [J].

SCHWARTZ, J ;

CANNON, JB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (17) :6226-&

[8]

VANLEEUWEN PWNM, 1994, RECL TRAV CHIM PAY B, V113, P61

← 1 →