DIASTEREOCONTROL IN INTERMOLECULAR DIELS-ALDER REACTIONS OF ALLENIC LACTONES - SYNTHETIC APPROACH TO THE PLAUNOLS

被引：9

作者：

JUNG, ME

ZIMMERMAN, CN

LOWEN, GT

KHAN, SI

机构：

[1] Department of Chemistry and Biochemistry, University of California, Los Angeles

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 28期

关键词：

D O I：

10.1016/0040-4039(93)88057-P

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diels-Alder cycloaddition of the allenic lactone 11 with 1-(1-(t-butyldimethylsilyloxy)vinyl)cyclohexene 6b produces the desired cycloadduct 12 with good endo selectivity (4:1) and excellent diastereoselectivity.

引用

页码：4453 / 4456

页数：4

共 18 条

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