ENANTIOSELECTIVE SYNTHESES OF (+)-METHYL NONACTATE AND (-)-METHYL 8-EPI-NONACTATE VIA ASYMMETRIC CYCLOADDITIVE ROUTE

被引：30

作者：

KIM, BH

LEE, JY

机构：

[1] Department of Chemistry, Center for Biofunctional Molecules, Pohang Institute of Science and Technology, Pohang, 790-600

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 18期

关键词：

D O I：

10.1016/S0040-4039(00)92241-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantioselective routes to (+)-methyl nonactate (2) and (-)-methyl 8-epi-nonactate (3) are described. The cornerstone of this synthetic strategy is a combination of asymmetric silyl nitronate cycloaddition and asymmetric reduction, which provides the key syn-1.3-diol intermediate 4.

引用

页码：2557 / 2560

页数：4

共 44 条

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