APPLICATION OF IRREVERSIBLE THERMODYNAMICS TO ELECTROKINETICS OF CHARGED SURFACE-LAYERS

被引：15

作者：

VOIGT, A ^{[1
]}

DONATH, E ^{[1
]}

KRETZSCHMAR, G ^{[1
]}

机构：

[1] HUMBOLDT UNIV,DEPT BIOL,BIOPHYS LAB,O-1040 BERLIN,GERMANY

来源：

COLLOIDS AND SURFACES | 1990年 / 47卷 / 01期

关键词：

Charged Surface Layers - Electrokinetics - Irreversible Thermodynamics - Poisson-Boltzmann Equation;

D O I：

10.1016/0166-6622(90)80059-D

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The present state of theoretical approaches to electrokinetics of charged surface layers of a finite thickness possessing a friction to hydrodynamic flow penetration is reviewed. Application of the basic rules of irreversible thermodynamics facilitates and generalizes the calculation procedure remarkably. Explicit expressions for the phenomenological coefficients of the electrokinetic phenomena at structured surfaces are presented here for the first time. For a fixed charge density profile, minimizing the electrostatic part of the free energy analytically closed expressions are derived based on solutions of the non-linearized Poisson-Boltzmann equation. © 1990.

引用

页码：23 / 34

页数：12

共 35 条

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