CHROMIUM(VI)-CATALYZED BENZYLIC OXIDATIONS WITH COMMERCIAL TERT-BUTYLHYDROPEROXIDE OR HYDROGEN-PEROXIDE

被引：44

作者：

MUZART, J

AJJOU, AN

机构：

[1] Unite de Recherche Rearrangements Thermiques et Photochimiques Associee au C.N.R.S., Université de Reims Champagne-Ardenne, 51062 Reims Cedex

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1991年 / 66卷 / 02期

关键词：

D O I：

10.1016/0304-5102(91)80008-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The factors influencing the efficiency of chromium(VI)-catalyzed benzylic oxidations were examined using indane as starting material. An 86% yield of alpha-indanone was reached in methylene chloride with 0.05 equiv of CrO3 and 4 equiv of 70% t-BuOOH as oxidant, while Cr(VI)-30% H2O2 led only to low yields.

引用

页码：155 / 161

页数：7

共 32 条

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