GEMINATE RECOMBINATION AFTER BINARY PHOTOIONIZATION

被引：74

作者：

BURSHTEIN, AI

机构：

[1] Department of Chemical Physics, Weizmann Institute of Science, Rehovot

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 194卷 / 03期

关键词：

D O I：

10.1016/0009-2614(92)85542-I

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A kinetic law is derived for geminate recombination which results from binary encounters of photoexcited donor with electron acceptors in liquid solution. The initial distribution over ion pair separation is found for both slow and fast ionization. When ionization is controlled by diffusion, the spherical reaction layer, where ions are mainly born, is shown to have a greater radius than the closest-approach distance.

引用

页码：247 / 251

页数：5

共 21 条

[1] CHARGE RECOMBINATION PROCESS OF ION-PAIR STATE PRODUCED BY EXCITATION OF CHARGE-TRANSFER COMPLEX IN ACETONITRILE SOLUTION - ESSENTIALLY DIFFERENT CHARACTER OF ITS ENERGY-GAP DEPENDENCE FROM THAT OF GEMINATE ION-PAIR FORMED BY ENCOUNTER BETWEEN FLUORESCER AND QUENCHER [J].