GRAFTING MALEIC-ANHYDRIDE AND COMONOMERS ONTO POLYETHYLENE

被引:99
作者
SAMAY, G [1 ]
NAGY, T [1 ]
WHITE, JL [1 ]
机构
[1] UNIV AKRON, INST POLYMER ENGN, AKRON, OH 44325 USA
关键词
D O I
10.1002/app.1995.070561105
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Grafting dicarboxylic anhydrides onto polyolefins has great practical importance. The process of grafting maleic anhydride onto high-density polyethylene in the presence of various comonomers in an intermeshing corotating twin-screw extruders was studied. Three types of comonomers were investigated: (i) vinyl monomers, including styrene and methacrylic acid; (ii) esters of dicarboxylic acids forming succinic groups after grafting, such as fumaric acid; and (iii) esters of fumaric and maleic acid and ethylenically unsaturated cyclic dicarboxylic anhydrides, such as Diels-Alder adducts of maleic anhydride; and (iv) dienes and dodecenyl succinic anhydride. (C) 1995 John Wiley & Sons, Inc.
引用
收藏
页码:1423 / 1433
页数:11
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