MOLECULAR-COMPLEX OF A CATIONIC PORPHYRIN AND PARA-NITROPHENOL - VERIFICATION OF THE PORPHYRIN DIMERIZATION

被引：17

作者：

KANO, K

HASHIMOTO, S

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 02期

关键词：

D O I：

10.1246/bcsj.63.633

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Complexation between 4,4',4'',4'''-(21H,23H-porphine-5,10,15,20- tetrayl)tetrakis[1-methylpyridinium] chloride (TMPyP) and ρ-nitrophenol has been studied in water. Upon the addition of ρ-nitrophenol, the coalesced fluorescence Q bands of TMPyP are resolved into well-separated Q(0-0) and Q(0-1) bands and the fluorescence decay comes to involve two exponential components. These results can be explained by the dimer model of TMPyP.

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页码：633 / 635

页数：3

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