A FOCK-SPACE COUPLED-CLUSTER METHOD FULLY UTILIZING VALENCE UNIVERSAL STRATEGY

被引:35
作者
MEISSNER, L
机构
[1] Institute of Physics, Nicholas Copernicus University
关键词
D O I
10.1063/1.470168
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An alternative formulation of the Fock-space coupled-cluster method using the hole-particle model spaces that fully exploits valence universal hierarchy of solving the coupled-cluster equations is presented. Formalism employs similarity transformations to separate eigenvalue problems for valence sectors with different numbers of quasiparticles but the same number of particles and that leads to certain simplifications in comparison with the previous formulations. These simplifications appear in the higher sectors that recently have been a subject of growing interest. The linked-cluster theorem is proven for the method. (C) 1995 American Institute of Physics.
引用
收藏
页码:8014 / 8021
页数:8
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